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Zunli Lu

Zunli Lu


Associate Professor and Director of Graduate Studies
Earth Sciences

zunlilu(at)syr.edu

310 Heroy Geology Laboratory
315.443.0281


In the news

Reduced Oxygen During Ice Age Sheds Light on ‘Missing’ Carbon Dioxide

Microfossils Reveal Warm Oceans Had Less Oxygen, Syracuse Geologists Say

Geologists Confirm Oxygen Levels of Ancient Oceans

Researchers work to fingerprint hydrofracking water quality

Scientists use rare mineral to correlate past climate events in Europe, Antarctica

Excellence in graduate education faculty recognition award

Research and Teaching Interests

Trace elements in carbonate and paleo-redox
Global warming will affect marine ecosystems in complex ways. The lower oxygen solubility at higher temperatures could lead to a decrease in dissolved oxygen (deoxygenation). This would severely impact ocean life (including valuable fisheries) because oxygen is necessary for eukaryotic organisms, and plays an important role in biogeochemical cycling of carbon, nitrogen and other biochemically important elements. Forecasting ocean chemistry changes during perturbation of the climate system relies on the development of computer models and their calibration using proxy data on the state of the oceans. Development of geochemical proxies thus is key to enable us to use geological records to predict potential consequences of global warming. I'm interested in developing new and sensitive proxies for oxygenation, to investigate changes in oceanic redox conditions during abrupt warm events and oceanic anoxic events in the geological past. Currently, I'm focusing on iodine proxy in carbonate rocks and micro-fossils.


Early diagenesis and authigenic carbonate (ikaite)
Complex biogeochemical reactions take place within the buried marine sediments, altering compositions of both solid phase sediments and their ambient porewaters. Organic matter diagenesis commonly lifts the levels of dissolved inorganic carbon and other solutes. Authigenic carbonate minerals can form under such condition. I'm interested in ikaite crystals (CaCO3·6H2O), a metastable hydrated carbonate mineral, that can precipitate rapidly in shallow sediment columns at relatively low temperature. Ikaite releases the hydration water at higher temperature, but may remain its macro-structure (pseudomorph, called glendonite) in outcropped old sedimentary rocks. Ikaite and glendonite have been used as indicators of cold bottom waters. The hydration water of ikaite also records oxygen isotopic composition of bottom water (or porewater), and may provide interesting information about past climate changes.


Porewater modeling
As a low temperature geochemist, I find that models are very useful tools for interrogating analytical data. I investigated glacial meltwater events in Antarctic fjords during the Anthropocene, by adapting the pioneering approach of modeling trends in δ18O in the porewaters of deep-sea cores, previously used to constrain the size of ice sheets during the Last Glacial Maximum. I hope to apply this approach in fjords of different sedimentary settings to reconstruct the glacier history and allow insight into the sensitivity of polar glaciers to abrupt warming events. Using a similar solute-transport-reaction model, I also looked at the halogen systematics in pore fluids of marine gas hydrate fields. Numerical model helped to quantify contributions of different sources to the porewater halogen pool, especially the iodine.


Gas hydrate, carbon and fluids in subduction zones
Large amount of methane are produced in marine sediments during organic matter decomposition and stored in gas hydrates. Gas hydrates may be an alternative energy source but global warming may also cause the dissociation of gas hydrates and massive release of gas. Many gas hydrate fields locate in subduction zones, close to the trench. Because of the tectonic compaction, hydrate fields are commonly featured with ubiquitous fluid conduits. Gas and fluid can migrate freely along these pathways up to very long distances. I use I-129 isotope to derive the age of organic source rocks of methane in subduction zones and learn about the long-term recycling of organic carbons.

Courses

EAR 419/619 Environmental Aqueous Geochemistry
The goal for this course is to teach fundamental principles of aqueous geochemistry in a broad context of the Earth surface system including both terrestrial and marine settings. I will introduce basic analytical methods and geochemical models, that are commonly used to solve water related problems. Real-life dataset from applied environmental studies are also used. I will touch upon some frontier research topics in Earth Sciences after going through the necessary and closely relevant background. For example, carbonate chemistry and weathering will be taught in association with global carbon cycle, glacial/interglacial climate change and ocean acidification. Students interested in topics about paleoclimate or global environmental changes are encouraged to take this class as well.

EAR 400/600 Chemical and Paleo Oceanography
Basic chemistry can be powerful for understanding the modern/past ocean circulations, the associated biological processes and the role of oceans in moderating climate. Traditional, novel tracers/proxies and computer models will be introduced. In addition to the focus on modern seawaters, this class also covers topics about pore waters and changes in water/sediment columns occurred in the past with relevance to the future. Students can explore existing big data sets with interactive tools. Hands on lab experiences are also possible.


EAR 111 Climate Change Past and Present
This course is designed to introduce students of all disciplines to the science behind our understanding of Earth's climate system and changes in that system through time. Topics discussed in the class will include:
- The fundamentals of the climate system from the sun to the atmosphere to the oceans
- Overview of climate changes throughout the history of the Earth
- Past climate change from geological records
- Climate system driving forces and their interactions
- Natural vs. anthropogenic (human forced) climate change
- Impacts of climate change on natural systems and human activities
- Future predictions and their reliability
- Evaluating solutions to climate change on a variety of scales
 

EAR 205 Water and the Environment
Investigates origin, occurrence, chemistry and hydrology of water on earth. Includes climate change, contamination and water supply issues within context of water sustainability.

Students

  • Kristina Gutchess (PhD)
  • Wanyi Lu (PhD)
  • Shannon Garvin (MS)

Former graduate students

  • Xiaoli Zhou  (PhD)
  • Sunshyne Hummel  (MS)

Facilities

Lab spaces include a general chemistry lab, a clean lab, and also instrument room.
A new generation quadrupole ICP-MS, Bruker Aurora M90


Low Temperature Geochemistry Facilities

Publications

*student authors

38. *Zhou, X., Jenkyns, H. C., *Lu, W., Hardisty, D. S., Owens, J. D., Lyons, T. W., and Lu, Z., 2017, “Organically bound iodine as a bottom-water redox proxy: preliminary validation and application”. Chemical Geology.

37. Hardisty, D.S., Lu, Z., Bekker, A., Diamond, C.W., Gill, B.C., Jiang, G., Kah, L.C., Knoll, A.H., Loyd, S.J., Osburn, M.R., Planavsky, N.J., Wang, C., *Zhou, X., Lyons, T.W., 2017. "Perspectives on Proterozoic surface ocean redox from iodine contents in ancient and recent carbonate". Earth and Planetary Science Letters 463, 159-170.

36. Owens, J.D., Lyons, T.W., Hardisty, D.S., Lowery, C., Lu, Z., Lee, B., and Jenkyns H.C., 2017. “Patterns of local and global redox variability during the Cenomanian–Turonian Boundary Event (OAE 2) recorded in carbonates and shales from central Italy”. Sedimentology. doi:10.1111/sed.12352.

35. *Zhou, X., Thomas, E., Winguth, A., Ridgwell, A., Scher, H., Rickaby, REM, and Lu, Z., 2016. “Expanded oxygen minimum zones during the late Paleocene - early Eocene: hints from multi-proxy comparison and ocean modeling”. Paleoceanography, 31, doi:10.1002/2016PA003020.

34. *Gutchess, K.M., Jin, L., Lautz, L.K., Shaw, S.B., *Zhou, X., Lu, Z., 2016, “Chloride sources in urban and rural headwater catchments, central New York”. Science of the Total Environment, 565, 462–472.

33. Lu, Z., Hoogakker, B.A.A., Hillenbrand C.D., *Zhou, X., Thomas, E., *Gutchess, K., *Lu, W., Jones, L., Rickaby, R.E.M., 2016, “Oxygen depletion recorded in upper waters of the glacial Southern Ocean”. Nature Communications, 7:11146 doi: 10.1038/ncomms11146.

32. Christian, K.M., Lautz, L.K., Hoke, G.D., Siegel, D.I., Lu, Z., Kessler, J., 2015 “Methane occurrence is associated with sodium-rich valley waters in domestic wells overlying the Marcellus Shale in New York State”. Water Resources Research, 52, 206–226, doi:10.1002/2015WR017805.

31. Jin, L., Edmunds, M.W., Lu, Z., Ma, J., 2015, “Geochemistry of sediment moisture in the Badain Jaran desert: Insights into palaeo-environmental changes and water rock interaction”.  Applied Geochemistry, 63, 235-247.

30. *Zhou, X., Jenkyns, H.C., Owens, J.D., Junium, C.K., Zheng, X., Sageman, B.B., Hardisty, D.S., Lyons, T.W., Ridgwell, A., and Lu. Z., 2015, The I/Ca proxy and upper ocean oxygenation dynamics across the Cenomanian–Turonian OAE 2. Paleoceanography, 30, 510–526. doi:10.1002/2014PA002741.

29. *Zhou, X., Lu, Z., Rickaby, R.E.M., Domack, E., and Wellner, J., "Ikaite abundance controlled by porewater phosphorus level: potential links to dust and productivity". Journal of Geology, Vol. 123, No. 3, pp. 269-281.

28. Lu, Z., *Hummel, S.T., Lautz, L.K., Hoke, G.D., Zhou, X., Leone, J., and Siegel, D.I., 2015, “Iodine as a sensitive tracer for detecting influence of organic-rich shale in shallow groundwater”. Applied Geochemistry, Vol. 60, pp. 29–36.

27. *Zhou, X., Thomas, E., Rickaby, R.E.M., Winguth, A.M.E., and Lu, Z., 2014, “I/Ca evidence for upper ocean deoxygenation during the Paleocene‐Eocene Thermal Maximum (PETM)”. Paleoceanography, DOI: 10.1002/2014PA002702.

26. Lautz, L.K., Hoke, G.D., Lu, Z., Siegel, D.I., Christian, K., Kessler, J.D., and Teale, N.G., 2014, “Using Discriminant Analysis to Determine Sources of Salinity in Shallow Groundwater Prior to Hydraulic Fracturing”. Environmental Science & Technology, 48 (16), 9061-9069.

25. Hardisty, D.S., Lu, Z., Planavsky, N.J., Bekker, A., Philippot, P., Zhou, X. and Lyons T.W., 2014, “An iodine record of Paleoproterozoic surface ocean oxygenation”. Geology, G35439. 1.

24. Limburg, K.E., Walther, B.D., Lu, Z., Jackman, G., Mohan, J., Weber, P.K., Schmitt, A.K., 2015, “In search of the dead zone: use of otoliths for tracking fish exposure to hypoxia”. Journal of Marine Systems, 141, 167-178.

23. Lu, Z., 2013, Comment on “Iodine-129 and Iodine-127 Speciation in Groundwater at the Hanford Site, U.S.: Iodate Incorporation into Calcite”. Environmental Science & Technology, 47 (22), pp.13203–13204. DOI: 10.1021/es404049s

22. Jin, L., Whitehead, P.G., Futter, M.N. and Lu, Z., 2012, Modeling the impacts of climate change on flow and nitrate of the River Thames: Assessing potential adaption strategies. Hydrology Research, vol. 43, pp.902-916. doi: 10.2166/nh.2011.080

21. Jin, L., Siegel, D.I., Lautz, L.K., and Lu, Z., 2012, Identifying streamflow sources during spring snowmelt using water chemistry and isotopic composition in semi-arid mountain streams. Journal of Hydrology, vol. 470–471, pp. 289–301

20. Lu, Z., Rickaby, R.E.M., Kennedy H., Kennedy, P., Shaw S., Lennie, A., Pancost, R.D., Wellner, J., and Anderson, J.B., 2012, An ikaite record of late Holocene climate at the Antarctic Peninsula. Earth and Planetary Science Letters, vol.325-326, pp. 108-115, doi:10.1016/j.epsl.2012.01.036 

19. Küpper, F. C., Feiters, M. C., Olofsson, B., Kaiho, T., Yanagida, S., Zimmermann, M. B., Carpenter, L. J., Luther, G. W., Lu, Z., Jonsson, M. and Kloo, L. (2011), Commemorating Two Centuries of Iodine Research: An Interdisciplinary Overview of Current Research. Angewandte Chemie International Edition, 50: 11598–11620. doi: 10.1002/anie.201100028

18. Lu, Z., Tomaru, H., and Fehn, U., 2011, Comparison of iodine dates from mud volcanoes and gas hydrate occurrences: relevance for the movement of fluids and methane in active margins. American Journal of Science. Vol. 311, (632–650), DOI 10.2475/07.2011.03

17. Lu, Z., Jenkyns, H.C., and Rickaby, R.E.M., 2010, Iodine to calcium ratios in marine carbonate as a paleo-redox proxy during oceanic anoxic events. Geology, 38(12), 1107–1110.

16. Lu, Z., Rickaby, R.E.M., Wellner, J., Georg, B., Charnley, N., Anderson, J.B. and Hensen C., 2010. Pore fluid modeling approach to identify recent meltwater signals on the west Antarctic Peninsula. Geochem. Geophys. Geosyst., 11, Q06017, Doi 10.1029/2009gc002949.

15. Scholz, F., Hensen, C., Lu, Z., and Fehn, U., 2010. Controls on the I-129/I ratio of deep-seated marine interstitial fluids: 'Old' organic versus fissiogenic 129-iodine. Earth and Planetary Science Letters, 294(1-2), 27-36.

14. Lu, Z., Fehn U., Zhao X., Kieser W.E. and Tomaru H., 2010, Comparison of three chemical extraction methods for I-129 determinations: Nuclear Instruments and Methods in Physics Research B, 268, 952–955.

13. Tomaru, H., Fehn, U., Lu, Z., Takeuchi, R., Inagaki, F., Imachi, H., Kotani, R., Matsumoto R., and Aoike, R., 2009, Dating of Dissolved Iodine in Pore Waters from the Gas Hydrate Occurrence Offshore Shimokita Peninsula, Japan: 129I Results from the D/V Chikyu Shakedown Cruise. Resource Geology, 59(4), 359-373.

12. Tomaru, H., Lu, Z., Fehn, U., and Muramatsu Y., 2009, Origin of hydrocarbons in the Green Tuff region of Japan: 129I results from oil field brines and hot springs in the Akita and Niigata Basins : Chemical Geology, v. 264, p. 221-231.

11. Lu, Z., Hensen, C., Fehn, U., and Wallmann, K., 2008, Halogen and 129I systematics in gas hydrate fields at the northern Cascadia margin (IODP Expedition 311): Insights from numerical modeling: Geochem. Geophys. Geosyst., 9, Q10006, doi:10.1029/2008GC002156.

10. Lu, Z., Tomaru, H., and Fehn, U., 2008, Iodine ages of pore waters at Hydrate Ridge (ODP Leg 204), Cascadia Margin: implications for sources of methane in gas hydrates: Earth and Planetary Science Letters, v. 267, p. 654-665.

9. Lu, Z., Hensen, C., Fehn, U., and Wallmann, K., 2007, Old iodine in fluids venting along the Central American convergent margin: Geophysical Research Letters 34, L22604, doi: 22610.21029/22007GL031864.

8. Lu, Z., Fehn, U., Tomaru, H., Elmore, D., and Ma, X., 2007, Reliability of 129I/I ratios produced from small sample masses: Nuclear Instruments and Methods in Physics Research B, v. 259, p. 359-364.

7. Tomaru, H., Lu, Z., Fehn, U., Muramatsu, Y., and Matsumoto, R., 2007 Age variation of pore water iodine in the eastern Nankai Trough, Japan: evidence for different methane sources in a large gas hydrate field: Geology, v.35, p.1015-1018.

6. Tomaru, H., Lu, Z., Snyder, G.T., Fehn, U., Hiruta, A., and Matsumoto, R., 2007, Origin and age of pore waters in an actively venting gas hydrate field near Sado Island, Japan Sea: interpretation of halogen and 129I distributions: Chemical Geology, v. 236, p. 350-366.

5. Tomaru, H., Fehn, U., Lu, Z.L., and Matsumoto, R., 2007, Halogen systematics in the Mallik 5L-38 gas hydrate production research well, Northwest Territories, Canada: Implications for the origin of gas hydrates under terrestrial permafrost conditions: Applied Geochemistry, v. 22, p. 656-675.

4. Tomaru, H., Ohsawa, S., Amita, K., Lu, Z.L., and Fehn, U., 2007, Influence of subduction zone settings on the origin of forearc fluids: Halogen concentrations and I-129/I ratios in waters from Kyushu, Japan: Applied Geochemistry, v. 22, p. 676-691.

3. Fehn, U., Lu, Z., and Tomaru, H., 2006, Data Report: 129I/I ratios and halogen concentrations in pore water of Hydrate Ridge and their relevance for the origin of gas hydrates: A progress report: Proceedings of the Ocean Drilling Program, Scientific Results, v. 204.

2. Lu, Z., Ling, H.F., Zhou, F., Jiang, S., Chen, X., and Zhou, H., 2005, Variation of the Fe/Mn ratio of ferromanganese crusts from the Central North Pacific: implication for paleoclimate changes: Progress in Natural Science, v. 15, p. 530-537.

1. Ling, H.F., Jiang, S.Y., Frank, M., Zhou, H.Y., Zhou, F., Lu, Z.L., Chen, X.M., Jiang, Y.H., and Ge, C.D., 2005, Differing controls over the Cenozoic Pb and Nd isotope evolution of deepwater in the central North Pacific Ocean: Earth and Planetary Science Letters, v. 232, p. 345-361.